Effects Of High Phosphate In Boiler Water

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  • pH Treatment | CleanBoiler.org

    Caustic attack on boilers is a localized attack due to extremely high pH (12.9 +). It can take two forms: caustic gouging or caustic cracking, also called caustic embrittlement. Caustic attack or caustic corrosion, is often encountered in phosphate treated boilers in which deposits of phosphates or other 'scale' occur in high heat transfer Get Price

  • Boiler Water Treatment Guidelines; Columbia Boiler Co

    Phosphates are used to react with calcium hardness in the boiler water. In order for this reaction to take place it is important to maintain a pH at a minimum value of 9.50. It is desirable to keep the concentration of phosphates in the water to 30 - 50 PPM in order for complete reaction of the phosphates with the calcium hardness entering the Get Price

  • Ph And Phosphate Concentration In Bfw And Steam Drum

    Oct 14, 2007 · Ph And Phosphate Concentration In Bfw And Steam Drum - posted in Industrial Professionals: Boiler feed water (BFW) pH is to be maintained in the range of 8.0 to 9.5(guidelines) where as in steam drum pH maintaining guidelines is in the range of 9.5 to 11.0. Pressure of steam drum is 34 barg. Since dosing of PO4 (Trisodium phosphate is dosing in …Get Price

  • Steam Purity - boiler-wrba.org

    •Foaming in the boiler caused by organic contamination (oil, high total organics from the makeup water, high boiler water TDS). •High chemical contamination caused by excessive TDS due to lack of boiler blowdown. •Excessive alkalinity due to excess hydroxide feed in the boiler water.Get Price

  • What problem does a significant concentration of Cl ion

    The main aspects are the great temperature difference and high pH. A boiler water sample has an unneutralised conductivity of 5 000 μS/cm at 25°C. What is the conductivity of the boiler water at 10 bar g? ses at the rate of approximately 2% (of the value at …Get Price

  • Boiler water chemistry - Properties of feed water explored

    Jul 16, 2009 · 7. Phosphates. Proper check on phosphates reserve of boiler water should be kept because it reacts with calcium and forms calcium phosphates, which is a major scale forming component. When calcium phosphates is formed it precipitates on the water surface and can be easily removed by blow down.Get Price

  • Why is phosphate dosing done in a boiler? - Quora

    Calcium phosphate is virtually insoluble in boiler water. Even small levels of phosphate can be maintained to ensure the precipitation of calcium phosphate in the bulk boiler water-away from heating surfaces. Therefore, the introduction of phosphate treatment eliminated the problem of calcium carbonate scale.Get Price

  • Water Handbook -Boiler Deposits: Occurrence And …

    Feb 06, 2020 · 4.6/5 (78 Views . 39 Votes) The most basic answer is: Phosphates help breakdown AND gather minerals and impurities in boiler water. It groups them together to form Sludge- that falls out of solution. It makes it possible for these compounds to form "mud"…. Further detail about this can be seen here.Get Price

  • (PDF) Boiler Water Analysis | John Arnold Oblena

    The result warns us against possible formation of carbonic acid inside the boiler as well as in the steam condensate lines, due to high concentration of bicarbonates EFFECT OF ALKALINITY Carbonate and bicarbonate alkalinities can combine with calcium and magnesium hardness to form scale in the boiler water system When heated, broken down to Get Price

  • Conductivity and pH of boiler water when using tri-sodium

    The most usual internal water treatment for low pressure boilers working below 600 PSI is to add trisodium phosphate (TSP) into boiler drum, reacting with water at …Get Price

  • Phosphate concentration-pH of boiler water when using

    one mole of trisodium phosphate will increase boiler water pH Correcting the dosage of phosphate if the Although high pressure boilers and the . High-Pressure Steam Cycle and Boiler Water Treatment. High Pressure Boilers – As trisodium phosphate hydrolyzes in the water it produces a hydroxyl ion (OH) boiler water treatmentGet Price

  • effect of hardness of water in industrial boilers

    Nov 01, 2017 · Effects of High TDS Levels in Feed Water to Boiler – Thermodyne … Jan 25, 2017 … Total Dissolved Solids (TDS) are the impurities in boiler feed water that reduces … and calcium and these are mainly responsible for water hardness. … and 1000+ installations across all major industry segments using boilers.Get Price


    Dec 04, 2018 · Phosphate hideout is a phenomenon which may occur under certain conditions in high pressure boilers where initially phosphate "disappears" and …Get Price


    Effects of organic water treatment chemicals and their decomposition products [4, 22, 23] CF of boiler tubes Effect of high pH, NaOH [5] Hydrogen damage Effects of NaOH, acid phosphate [5, 26] Boiler tube corrosion Effects of "acid phosphates", maracite [5, 26, 27] Water droplet erosion Predictive equations, effects of chemistry [7, 28]Get Price


    In high pressure boilers, an excess of a soluble phosphate is added to the boiler water to precipitate the residual calcium ions in the form of a non-adherent precipitate of calcium phosphate and thus the scale formation is prevented. 20. Differentiate between drinking water and boiler feed water. S.No Drinking water Boiler feed waterGet Price

  • Water Treatment - Phosphate Specialty : Phosphate Specialty

    Boiler feedwater can be protected from corrosive conditions through coordinated phosphate/pH control treatment. Phosphate buffers the boiler water, reducing the chance of large pH swings due to the development of caustic concentrations. In phosphate treatment, excess caustic combines with disodium phosphate to form trisodium phosphate.Get Price

  • Application of Phosphates in Boiler Water Treatment

    Phosphate anti-scaling treatment is to add phosphate solution to keep a certain amount of phosphate radical in the boiler water. Therefore, the calcium ions in the boiler water will react with phosphate radical, the resulting basic calcium phosphate is a soft slag, which is easy to be removed with the boiler blowdown and won't adhere to the Get Price


    E14F-2 The tests that are run on the make-up feedwater and boiler water aboard ship are: 1. pH (phosphate buffer check): This test is run with a pH meter.Its purpose is to ensure that the water is about pH = 10.5.Get Price

  • Inexplicable pH drop in boiler blowdown water

    Jan 03, 2022 · 2006. Q. I would like to add on his question in relation to our plant. we have a high pressure boiler but we minimize our blowdown in relation to silica and pressure. in two months time without blowdown, we have observed decreasing pH in the feed and boiler water even with 2-3 ppm phosphate. our treatment if ammonia and hydrazine at the feedwater and TSP for the …Get Price

  • Boiler Water Treatment - Association of Water Technologies

    When the concentration of phosphate in the boiler water is too high, phosphate will react with boiler scale forming iron and iron sodium phosphates or precipitate to form a solid phase on the hot boiler tube surfaces and elsewhere.Get Price

  • Boiler water treatment - Lenntech

    The treatment and conditioning of boiler feed water must satisfy three main objectives:. Continuous heat exchange; Corrosion protection; Production of high quality steam; External treatment is the reduction or removal of impurities from water outside the boiler. In general, external treatment is used when the amount of one or more of the feed water impurities is too …Get Price

  • IS 10496 (1983): Feed Water, Boiler Water and Condensate

    Jan 07, 1983 · SPECIFICATION FOR FEED WATER, BOILER WATER AND CONDENSATE FOR HIGH PRESSURE BOILERS 0. FOREWORD 0.1 This Indian Standard was adopted by the Indian Standards Institution on 7 January 1983, after the draft finalized by the Boiler Water Sectional Committee had been approved by the Chemical Division Council.Get Price

  • What is the condition to start phosphate dosing in a high

    Answer (1 of 2): Generally the Phosphate dozing is done in the drum of the boiler. it helps to convert the calcium hard salts to soft sludge. the sludge is higher in weight,so it comes to the bottom of the drum . then it is removed by CBD. this is …Get Price

  • Effects of High Phosphate Levels in Water – Orlando

    When the concentration of phosphate in the boiler water is too high, phosphate will react with boiler scale forming iron and iron sodium phosphates or precipitate to form a solid phase on the hot boiler tube surfaces and elsewhere. This phenomenon is called phosphate hideout and it can result in changes of pH, as well as the concentrations ofGet Price

  • Boiler Water Treatment Chemicals, Feed, and Control

    The total calculation equation to remove residual oxygen and provide a boiler water residual is: (Feedwater O 2 x 7.88) + (1.6 x Boiler Water SO 3 Residual) / Feedwater Cycles = Feedwater Dosage of sodium sulfite in ppm. Spreadsheets can be made as shown at the end of the article that illustrate theGet Price


    May 02, 2000 · When boiler water pH is not within the proper range, calcium reacts with phosphate to form harmful calcium phosphate scale. Other impurities such as silica and iron can be tied up by dispersants and chelants and remain suspended in the boiler water where they can be removed by continuous surface or bottom blow down. Left improperly treatedGet Price

  • What is Carryover | Causes of Carryover

    The boiler water if contains high TDS the carryover of solids will be more. Since the efficiency of separator which is fixed, the only way to bring carryover is to bring down the Boiler water TDS. In boiler water, the presence of free NaOH must be eliminated by …Get Price

  • QUESTIONS AND ANSWERS Phosphate Hideout

    Phosphate hideout is a phenom-enon that causes boiler water control difficulties. It is defined as the disappearance, by precipita-tion or absorption, of the ionic phosphate (PO 4) species, in the boiler water under high heat transfer or high load conditions. When the high heat flux or high load condition is reduced, the species (phosphate Get Price

  • Phosphate Hideout

    Phosphate Hideout. When the concentration of phosphate in the boiler water is too high, phosphate will react with boiler scale forming iron and iron sodium phosphates or precipitate to form a solid phase on the hot boiler tube surfaces and elsewhere. This phenomenon is called phosphate hideout and it can result in changes of pH, as well as the Get Price

  • The International Association for the Properties of Water

    Makeup Water MU Water which is added to compensate for losses of water and steam from the system Mono-sodium phosphate MSP NaH2PO4 Once-through boiler or HRSG Benson Boiler Boiler in which output steam is generated from input water by complete evaporation. There is no recirculation of boiler water. Oxygenated Treatment OT Combined WaterGet Price

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